• R23

    Trifluoromethane

    CAS No.: 75-46-7 UN No.: 1984 CLASS No.: 2.2 Molecular formula: CHF₃

    It is mainly used as a low-temperature refrigerant and a fire extinguishing agent.

  • R23

    R23 (Trifluoromethane), also known as Fluoroform or CHF₃, is a colorless, non-flammable gas with a faint ethereal odor. With CAS registry number 75-46-7, it is classified as a hydrofluorocarbon (HFC) refrigerant with zero ozone depletion potential (ODP).

  • Applications

    Refrigeration & Cryogenics

    Laboratory freezers and environmental test chambers

    Medical and pharmaceutical cold storage

    Food freezing and preservation systems

    Superconducting magnet cooling

    Semiconductor Manufacturing

    Plasma etching of silicon-based materials

    Chamber cleaning in CVD and PVD processes

    Dielectric etching for advanced node semiconductors

    Fire Suppression

    R23's high density and non-flammable properties make it suitable for specialized fire suppression systems, particularly for protecting high-value electrical equipment.

    Research & Analytical Chemistry

    Supercritical fluid extraction (SFE)

    NMR spectroscopy as a fluorine source

    Atmospheric and climate research

    Chemical synthesis of fluorinated compounds

  • Physical & Chemical Properties

    Physical Properties

    Molecular Weight: 52.02 g/mol

    Boiling Point: (at 1 atm)-51.7 °C (-61.1 °F)

    Freezing Point: -136.8 °C (-214.2 °F)

    Critical Temperature: 78.1 °C (172.6 °F)

    Critical Pressure: 5.78 MPa (838 psia)

    Critical Density: 424 kg/m³

    Liquid Density (at 25°C): ~950 kg/m³

    Vapor Density (air=1): 1.8 (heavier than air)

    Specific Heat (Liquid, 25°C): ~1.57 kJ/(kg·K)

    Specific Heat (Vapor, 25°C): ~0.83 kJ/(kg·K)

    Thermal Conductivity: Higher than R410A, improving heat exchanger efficiency.

    Viscosity: Lower than R410A, reducing pressure drop in systems.

    Chemical & Safety Properties

    Flammability: Class A2L. Mildly flammable. It has a low burning velocity and a high Lower Flammability Limit (LFL), making it harder to ignite and sustain a flame compared to hydrocarbons.

    Lower Flammability Limit (LFL): 14.4% by volume in air.

    Upper Flammability Limit (UFL): 29.3% by volume in air.

    Auto-Ignition Temperature: 648 °C (1198 °F)

    ODP (Ozone Depletion Potential): 0 – Does not deplete the ozone layer.

    GWP (Global Warming Potential): 675 (IPCC AR5, 100-yr). This is about 1/3 of R410A's GWP (~2088).

    Atmospheric Lifetime: ~5.2 years (much shorter than R410A).

    Toxicity: Class A (Low Toxicity). However, at high concentrations, it can act as a simple asphyxiant and, like all refrigerants, decompose into toxic fumes (HF, carbonyl fluoride) if exposed to an open flame or extreme heat.

    Thermodynamic & Performance

    High Volumetric Cooling Capacity: Approximately 1.5 times greater than R410A. This means smaller displacement compressors can be used for the same cooling effect.

    C.O.P. (Coefficient of Performance): Similar to or slightly higher than R410A, offering good energy efficiency.

    Glide: Near Azeotropic (~0.5 K). It behaves almost like a single-component refrigerant, simplifying system design and service.

    Discharge Temperature: Higher than R410A, which requires specific compressor design considerations for reliability.

  • Packaging, Storage & Transportation

    Cylinder Sizes

    Available in 10 lb, 25 lb, 30 lb, 50 lb disposable cylinders. Also offered in 100 lb, 500 lb, 1,000 lb recovery cylinders for reclaimed R23.

    Storage Recommendations

    Store in a well-ventilated, dry area away from direct sunlight and heat sources

    Maintain storage temperature below 52°C (125°F)

    Keep containers tightly closed and properly labeled

    Store away from combustible materials and oxidizing agents

    Use first-in, first-out (FIFO) inventory system

    Transportation & Handling

    Transport in upright position and secure to prevent tipping

    Use appropriate personal protective equipment (safety glasses, gloves)

    Ensure adequate ventilation during transfer operations

    Use pressure-regulating equipment compatible with gas service

    Do not drop, drag, or roll cylinders

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